A dual purpose aluminum-based metal organic framework for the removal of chloramphenicol from wastewater
Gözmen, Belgin | Geçgel, Cihan | Görmez, Özkan | Turabik, Meral
The presence of antibiotics in the aquatic environment can cause significant environmental and human health problems even at trace concentrations. Conventional treatment systems alone are ineffective in removing these resistant antibiotics. To address this problem, oxidation and adsorption techniques were used to explore the removal of recalcitrant antibiotic chloramphenicol (CAP). An aluminum-based metal-organic framework (AlMIL) with high surface area and extended porosity, was prepared and used both as adsorbent and catalyst for the oxidation of CAP. Characterization of the Al-MIL revealed a large surface area of 1137 m2 g− 1 , a homogeneous microporous structure, good crystallinity, and particle size in the range of 200–400 nm. Adsorption of CAP on AlMIL achieved equilibrium afte...
CoFe2O4 nanoparticles decorated onto graphene oxide and graphitic carbon nitride layers as a separable catalyst for ultrasound-assisted photocatalytic degradation of Bisphenol-A
Görmez, Özkan | Gözmen, Belgin | Yakar, Ezgi
The advanced oxidation process (AOP) through ultrasound-assisted photocatalytic degradation has attracted much attention in removing emerging contaminants. Herein, CoFe2O4-GO and CoFe2O4-g-C3N4 nanocomposites were synthesized using the ultrasound-assisted co-precipitation method. TEM, XRD, XPS, EDS, SEM, and FT-IR techniques characterized the structural, morphological, and chemical properties of the synthesized nanocomposites. The analyses showed that CoFe2O4 structure was nano-sized and distributed more homogeneously in graphene oxide (GO) layers with oxygenated functional groups than graphitic carbon nitride (g-C3N4). While the efficiency of composite catalysts, as photocatalysts, for degradation of bisphenol-A (BPA) was low in the visible region in the presence of persulfate, thei...
Evaluation of sewage sludge biochar and modified derivatives as novel SPE adsorbents for monitoring of bisphenol A
Gözmen, Belgin | Sönmez, Özgür
Sewage sludge is abundant biomass, the sustainable management of which remains a big issue worldwide. It was demonstrated that pyrolysis of sewage sludge using simple and cost-effective apparatus can produce biochars, suitable for solid-phase extraction applications of hydrophobic analytes. Detailed characterization showed that modification lead to three more hydrophobic and one more hydrophilic sample, compared to the original biochar. All samples were evaluated in the solid-phase extraction of the emerging contaminant Bisphenol A from aqueous solutions. KOH-SSB and KOH/MeOH-SSB exhibited the most promising behavior, with the latter achieving recoveries of 88.1%, at a quantity of 0.1 g at the natural pH of the BPA solution (6.5). The effect of solution pH was insignificant in the range of...