Koleksiyon Enstitüler
170887

SANAT EĞİTİMİ VE ULUSLARARASI UYGULAMALAR

Can KÜÇÜKTEPEPINAR

Öz Bu çalışmada sanat eğitiminde müfredatın içeriği, ders saatleri, sanat eğitiminde bilgi ve iletişim teknolojilerinin kullanımı, sanat eğitimini desteklemek için kurulan uluslararası örgütler ve ağlar, sanat ile okul işbirliği, sanat eğitimini desteklemek için müfredat dışı kültürel faaliyetlerin organizasyonu, sanata ilişkin festivaller, yarışmalar, sempozyumlar ve kutlamalar, sanat eğitimini destekleyen girişimler ve sanat öğretmenlerinin eğitimi ve yetiştirilmesi incelenmiştir. Çalışmada sanata, sanat eğitiminin önemine değinilmiş, sanat eğitiminde geçmişten günümüze kadar uygulanmış yöntemler/yaklaşımlar üzerine belirlemelerde bulunulmuş ve bu kapsamda, çocuk merkezci yaklaşım, deneyci yaklaşım ve disiplin merkezci yaklaşım yöntemleri üzerine değinilmiştir. Dünya üzerindeki ülkeleri...

Makale2014ERCİYES SANAT 1 | 0 Erişime Açık
170179

JOHN CAGE: PREPARED PIANO (HAZIRLANMIŞ PİYANO)’NUN YİRMİNCİ YÜZYIL MÜZİĞİNDEKİ ETKİLERİ

DENİZ KAYA DOĞAN

JOHN CAGE: PREPARED PIANO (HAZIRLANMIŞ PİYANO)’NUN YİRMİNCİ YÜZYIL MÜZİĞİNDEKİ ETKİLERİ Özet Amerikalı Avangard besteci John Cage, 1930’lu yılların sonlarına doğru, birlikte çalıştığı Merce Cunningham, Bonnie Bird, Syvilla Fort gibi isimlerin dans koreografilerine eşlik etmek amacıyla Hazırlanmış Piyano için eserler yazmaya başladı. Hazırlanmış Piyano, tellerin üzerine veya arasına vida, cıvata, somun, lastik, silgi vb. malzemeler yerleştirilerek sesin karakterini ve tınısını değiştirebilme şansı elde edilen bir piyanodur. Bestecinin ilk hazırlanmış parçası olarak kabul edilen Bacchanale, küçük bir perküsyon grubunun tek bir enstrüman (hazırlanmış piyano) ile vurmalı bir orkestraya dönüştüğü eserdir. Bestecinin bir Hazırlanmış Piyano başyapıtı olarak bilinen eseri ise Sonatlar ve Int...

169757

New phosphine-amino-alcohol tridentate ligands for ruthenium catalyzed asymmetric transfer hydrogenation of ketones

Altan, Orhan | Yılmaz, Mustafa Kemal

New phosphine-amino-alcohol tridentate ligands (3a-c) and six new ruthenium complexes (4a-c and 5a-c) were synthesized and characterized. Catalytic activities of the metal complexes were tested on aryl alkyl ketones. All of the substrates were converted to related sec-alcohols in excellent yields (up to 99%), but enantioselectivities were insufficient (up to 40% ee). Despite the catalytic performance of 5a-c complexes can be considered as better than 4a-c, actually the catalytic activity of the complexes has been differed according to substrate. The ketones with less positive carbonyl carbons tend to give S-configuration with 5a-c and R-configuration with 4a-c. The catalytic performance of the complexes was rationalized by means of DFT calculations.

169772

Nanostructured Photocatalysts Chapter 15 - Black phosphorus-based photocatalysts for energy and environmental applications

Altan, Orhan

Photocatalysis using semiconductor materials to conduct chemical reactions more efficiently with the aid of sunlight irradiation is foreseen as a promising solution to combat the energy and environmental pollution crisis that the world is facing at present. Finding a suitable semiconductor material that harvests a large portion of the sunlight spectrum with high photocatalytic efficiency lies in the heart of photocatalysis. In this regard, black phosphorus (BP), a rising star two-dimensional (2D) semiconducting material, has recently been regarded as an abundant, nontoxic, metal-free, and cheap photocatalyst with a suitable bandgap and broad light absorption ability. In this chapter, after the introduction of the general properties and synthesis of BP, the photocatalytic efficiency of BP a...

169777

Boosting formic acid dehydrogenation via the design of a Z-scheme heterojunction photocatalyst: The case of graphitic carbon nitride/Ag/Ag3PO4-AgPd quaternary nanocomposites

Altan, Orhan

The development of an efficient, eco-friendly, practical, and selective way to decompose formic acid (FA) into H2 and CO2 is crucial for the utilization of FA as a chemical hydrogen storage material in hydrogen economy. In this regard, photocatalytic FA dehydrogenation attracts great attention owing to its potential to meet the above-mentioned requirements. Interestingly, there is no example of heterojunction photocatalyst that tunes the hole potential of the semiconductor, resulted in a better photocatalytic activity. We report herein for the first time the design and fabrication of a novel Z-scheme heterojunction photocatalyst for FA dehydrogenation, denoted as g-CN/Ag/Ag3PO4-AgPd comprising graphitic carbon nitride (g-CN) and Ag3PO4 semiconductors, Ag and AgPd alloy nanoparticles (NPs)....

Makale2021Applied Surface Science 2 | 0 Erişime Kapalı
169802

The influence of band bending phenomenon on photocatalytic Suzuki-Miyaura coupling reaction: The case of AgPd alloy nanoparticles supported on graphitic carbon nitride

Altan, Orhan

The development of solar-powered systems for applications other than energy, such as photocatalytic organic reactions, will benefit in the resolution of environmental issues while also lowering production costs. In this study, the photocatalytic activity of g-CN(G)-AgPd, which was prepared by synthesizing AgPd alloy nanoparticles (NPs) on g-CN, was investigated in the Suzuki-Miyaura coupling (SMC) reaction. The photocatalytic activity of g-CN(G)-AgPd in an ethanol/water mixture at ambient temperature was discovered to be among the highest ever recorded. Under vis-light illumination, g-CN(G)-AgPd converted all of the aryl iodides and most of the aryl bromides investigated to desired coupling products in 15 min with excellent isolated yields, and it was used at least five times without signi...

Makale2022Applied Surface Science 2 | 0 Erişime Kapalı
169804

A rare example of the in situ formation of palladium nanoparticles: The emergence of catalytically active palladium nanoparticles from Pd (II) phosphine complexes in the Suzuki–Miyaura coupling reaction

Altan, Orhan

Suzuki–Miyaura coupling (SMC) reactions are one of the most promising routes for carbon–carbon bond formation. It is believed that metal complexes, particularly palladium complexes, are the most effective catalysts for this purpose. However, the catalysis nature whether it is homogenous or heterogeneous is under debate. It is commonly believed that a homogenous catalysis pathway is responsible for the catalytic activity when the phosphine ligands are present in the structure due to the strong phosphorus-metal interactions. In this study, Pd (II) complexes of phosphino-benzaldoxime ligands were synthesized, characterized, and tested in SMC reactions. Interestingly, it was found that the catalytic activity increased by 11 times when the amount of catalyst was reduced by 10-fold and increased...

169807

The rational design of a graphitic carbon nitride-based dual S-scheme heterojunction with energy storage ability as a day/night photocatalyst for formic acid dehydrogenation

Altan, Orhan

Photocatalytic formic acid dehydrogenation (FAD) has been regarded as one of the most promising methods of producing H2 in a sustainable manner. In the photocatalytic FAD reaction, photogenerated holes play an important role in the reaction mechanism and thus in the efficiency of photocatalysts. However, the design of photocatalytic systems capable of generating high hole potential without compromising the reducing ability of the photocatalyst is extremely rare for the FAD reaction. In this respect, we report herein a novel and highly efficient heterojunction photocatalyst composed of 2D graphitic carbon nitride, 2D MnO2, 1D MnOOH, and 0D PdAg alloy nanoparticles, denoted as GCN/MnO2/MnOOH-PdAg, that can create high reduction and oxidation potentials via a dual S-scheme heterojunction. The...

170009

Metaphoric Conceptualization of Love Pain or Suffering in Turkish Songs through Natural Phenomena and Natural Disasters

Muhammet Fatih Adıgüzel

Traditional Turkish love is identified with suffering. This study investigates how suffering in love is metaphorically conceptualized in Turkish via natural phenom ena and disasters. Based on figurative expressions in sad love songs of Arabesque and Art music genres, the study reveals that love pain/suffering is expressed through three salient metaphors: 1) LOVE PAIN/SUFFERING IS NATURAL PHENOMENA,2)LOVE PAIN/SUFFERING IS NATURAL DISASTERS, and 3) the overarching metaphor (the suffering) LOVER’SBODYISALANDSCAPE(affected by weather conditions or natural disasters). It was unearthed from metaphoric expressions in lyrics that as part of a cultural scenario, natural phenomena anddisastersareprofiledasinternalized forces culturally imagined to directly affect vital body parts to expres...

170011

A Cross-Lingual Study on Near-synonyms Deep and Profound in English and Profond in French: Implications for Foreign Language Education

Muhammet Fatih Adıgüzel | Muzaffer Pınar Babanoğlu

This corpus-based study investigates the cross-linguistic and intra-linguistic relationships among the English near-synonyms "deep" and "profound," and the French word "profond." By analyzing the collocative behaviors of these adjectives, the study aims to identify the contexts in which "deep" and "profound" are interchangeable and whether "profound" in English and "profond" in French are semanically and ollocatively equivalent. Collocations were extracted from the English corpus "50% Sample of ukWaC" and the French corpus "Europarl 3: French." The analysis revealed both cross-linguistic and intra-linguistic similarities and differences. Intra-linguistic similarities and differences were observed between "deep" and "profound" in English, while cross-linguistic comparisons were made between...

170012

Metaphoric Conceptualization of Love Pain or Suffering in Turkish Songs through Natural Phenomena and Natural Disasters

Muhammet Fatih Adıgüzel

suffering in love is metaphorically conceptualized in Turkish via natural phenom ena and disasters. Based on figurative expressions in sad love songs of Arabesque and Art music genres, the study reveals that love pain/suffering is expressed through three salient metaphors: 1) LOVE PAIN/SUFFERING IS NATURAL PHENOMENA,2)LOVE PAIN/SUFFERING IS NATURAL DISASTERS, and 3) the overarching metaphor (the suffering) LOVER’SBODYISALANDSCAPE(affected by weather conditions or natural disasters). It was unearthed from metaphoric expressions in lyrics that as part of a cultural scenario, natural phenomena anddisastersareprofiledasinternalized forces culturally imagined to directly affect vital body parts to express the emotional distress or anguish of the Turkish lover. The overarching metaphor LOVER...

Makale2020Metaphor and Symbol 1 | 0 Erişime Açık
170024

Corpus-driven Lexical Profiles of the Turkish Synonym Set Sadece, Yalnızca and Yalnız

Muhammet Fatih Adıgüzel

This is a corpus-driven study based on the TNCv3.0 to identify lexical profiles of the synonym set of Turkish exclusive adverbials sadece, yalnızca and yalnız within the framework of the Model of Extended Lexical Units (Stubbs, 2002). From the concordances of the adverbials, their context dependent semantic, pragmatic and syntactic properties, co-occurrence tendencies, and synonymity levels were identified. It was found that sadece and yalnızca have a high contextual and collocational equinormality and are completely intersubstitutable and complete synonyms (Lyons, 1981) with yalnızca used less frequently. Yalnız is polysemous and multifunctional and has a sense synonymy relation with the others only when it means only. Even in the sense of only, yalnız was found to be rarely used in cer...

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