Two non-linear azide containing heteronuclear complexes: crystal structure and thermal decomposition

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Kurum Dışı Yazarlar	Öz, Sevi Kurtaran, R. Arıcı, C. Ergün, Ü. Emregül, K. C. Atakol, Orhan Ülkü, D.
Tek Biçim Adres (URI)	https://hdl.handle.net/20.500.14114/8076
Yayın Türü	Makale
Yayın Yılı	2010
DOI Adresi	10.1007/s10973-009-0172-7
Yayıncı	Springer
Dergi Adı	Journal of thermal analysis and calorimetry
Konu Başlıkları	Azide containing complexes Explosives Molecular structure TG
İndekslenen Platformlar	Web of Science

Bis-N,N'(salicylidene)-2,2'-dimethyl-1,3-propanediamine (LDMH2) has a high tendency to form polynuclear complexes. Two trinuclear complexes were obtained using this ligand and azide ions; (CuLDM)(2) center dot A Mn(N-3)(2) center dot A (DMF)(2), [(C19H20N2O2Cu)(2) center dot A Mn(N-3)(2) center dot A (C3H7NO)(2)] and (CuLDM)(2) center dot A Cd(N-3)(2) center dot A (DMF)(2), [(C19H20N2O2Cu)(2) center dot A Cd(N-3)(2) center dot A (C3H7NO)(2)]. The structures were identified with X-ray methods. TG and DSC methods were also employed to these complexes. Studies showed the (CuLDM)(2) center dot A Mn(N-3)(2) center dot A (DMF)(2) and (CuLDM)(2) center dot A Cd(N-3)(2) center dot A (DMF)(2) to be non-linear. Also mu-bridges were not encountered for the azide ions but were seen to form between the Cu and other metal via phenolic oxygens. Thermal analysis showed exothermic degradation of the azide ions destroying the trinuclear structure. Although azide containing structures show explosive characteristics, this was not observed for the present compounds.

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Eser Adı dc.title	Two non-linear azide containing heteronuclear complexes: crystal structure and thermal decomposition
Kurum Dışı Yazarlar dc.contributor.other	Öz, Sevi
Kurum Dışı Yazarlar dc.contributor.other	Kurtaran, R.
Kurum Dışı Yazarlar dc.contributor.other	Arıcı, C.
Kurum Dışı Yazarlar dc.contributor.other	Ergün, Ü.
Kurum Dışı Yazarlar dc.contributor.other	Emregül, K. C.
Kurum Dışı Yazarlar dc.contributor.other	Atakol, Orhan
Kurum Dışı Yazarlar dc.contributor.other	Ülkü, D.
Yayıncı dc.publisher	Springer
Yayın Türü dc.type	Makale
Özet dc.description.abstract	Bis-N,N'(salicylidene)-2,2'-dimethyl-1,3-propanediamine (LDMH2) has a high tendency to form polynuclear complexes. Two trinuclear complexes were obtained using this ligand and azide ions; (CuLDM)(2) center dot A Mn(N-3)(2) center dot A (DMF)(2), [(C19H20N2O2Cu)(2) center dot A Mn(N-3)(2) center dot A (C3H7NO)(2)] and (CuLDM)(2) center dot A Cd(N-3)(2) center dot A (DMF)(2), [(C19H20N2O2Cu)(2) center dot A Cd(N-3)(2) center dot A (C3H7NO)(2)]. The structures were identified with X-ray methods. TG and DSC methods were also employed to these complexes. Studies showed the (CuLDM)(2) center dot A Mn(N-3)(2) center dot A (DMF)(2) and (CuLDM)(2) center dot A Cd(N-3)(2) center dot A (DMF)(2) to be non-linear. Also mu-bridges were not encountered for the azide ions but were seen to form between the Cu and other metal via phenolic oxygens. Thermal analysis showed exothermic degradation of the azide ions destroying the trinuclear structure. Although azide containing structures show explosive characteristics, this was not observed for the present compounds.
Kayıt Giriş Tarihi dc.date.accessioned	2025-12-25
Yayın Yılı dc.date.issued	2010
Açık Erișim Tarihi dc.date.available	2999-01-01
Dil dc.language.iso	eng
Konu Başlıkları dc.subject	Azide containing complexes
Konu Başlıkları dc.subject	Explosives
Konu Başlıkları dc.subject	Molecular structure
Konu Başlıkları dc.subject	TG
Atıf İçin Künye dc.identifier.citation	Öz, S., Kurtaran, R., Arıcı, C., Ergun, Ü., Kaya, F. D., Emregül, K. C., ... & Ülkü, D. (2010). Two non-linear azide containing heteronuclear complexes: crystal structure and thermal decomposition. Journal of thermal analysis and calorimetry, 99(1), 363-368.
ISSN dc.identifier.issn	1388-6150
İlk Sayfa dc.identifier.startpage	363
Son Sayfa dc.identifier.endpage	368
Makale Numarası dc.identifier.articlenumber	-
Dergi Adı dc.relation.journal	Journal of thermal analysis and calorimetry
Dergi Sayısı dc.identifier.issue	1
Dergi Cilt dc.identifier.volume	99
Tek Biçim Adres (URI) dc.identifier.uri	https://link.springer.com/content/pdf/10.1007/s10973-009-0172-7?utm_source=clarivate&getft_integrator=clarivate
Tek Biçim Adres (URI) dc.identifier.uri	https://hdl.handle.net/20.500.14114/8076
DOI Numarası dc.identifier.doi	10.1007/s10973-009-0172-7
İndekslenen Platformlar dc.source.database	Web of Science

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