Pd(II) complexes of novel phosphine ligands: Synthesis, characterization, and catalytic activities on Heck reaction

Altan, Orhan

doi:10.1080/10426507.2015.1119827

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Yazarlar	Altan, Orhan
Kurum Dışı Yazarlar	Serindağ, Osman Sayın, Koray Karakaş, Duran
Tek Biçim Adres (URI)	https://hdl.handle.net/20.500.14114/8218
Yayın Türü	Makale
Yayın Yılı	2016
DOI Adresi	https://doi.org/10.1080/10426507.2015.1119827
Yayıncı	Taylor & Francis
Dergi Adı	Phosphorus, Sulfur, and Silicon and the Related Elements
Konu Başlıkları	Metal complexes phosphine Heck C-C eşleşme Homogeneous catalysts
İndekslenen Platformlar	Web of Science

Novel phosphine oxides, (((3-methylpyridin-2-yl)amino)methyl)diphenylphosphine oxide (1) and diphenyl((pyrazin-2-ylamino)methyl)phosphine oxide (2), were synthesized and characterized. Phosphines ligands (3 and 4) were obtained by the reduction of 1 and 2 with AlH3, monitored by 31P NMR spectroscopy. Pd(II) complexes of 3 and 4 were synthesized and characterized (5 and 6). The catalytic activity of 5 and 6 was tested on the reaction of styrene with both activated and deactivated aryl bromides in air. The results of the catalytic experiments were discussed through DFT calculations.

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Eser Adı dc.title	Pd(II) complexes of novel phosphine ligands: Synthesis, characterization, and catalytic activities on Heck reaction
Yazarlar dc.contributor.author	Altan, Orhan
Kurum Dışı Yazarlar dc.contributor.other	Serindağ, Osman
Kurum Dışı Yazarlar dc.contributor.other	Sayın, Koray
Kurum Dışı Yazarlar dc.contributor.other	Karakaş, Duran
Yayıncı dc.publisher	Taylor & Francis
Yayın Türü dc.type	Makale
Özet dc.description.abstract	Novel phosphine oxides, (((3-methylpyridin-2-yl)amino)methyl)diphenylphosphine oxide (1) and diphenyl((pyrazin-2-ylamino)methyl)phosphine oxide (2), were synthesized and characterized. Phosphines ligands (3 and 4) were obtained by the reduction of 1 and 2 with AlH3, monitored by 31P NMR spectroscopy. Pd(II) complexes of 3 and 4 were synthesized and characterized (5 and 6). The catalytic activity of 5 and 6 was tested on the reaction of styrene with both activated and deactivated aryl bromides in air. The results of the catalytic experiments were discussed through DFT calculations.
Kayıt Giriş Tarihi dc.date.accessioned	2025-12-29
Yayın Yılı dc.date.issued	2016
Açık Erișim Tarihi dc.date.available	2099-01-01
Dil dc.language.iso	eng
Konu Başlıkları dc.subject	Metal complexes
Konu Başlıkları dc.subject	phosphine
Konu Başlıkları dc.subject	Heck C-C eşleşme
Konu Başlıkları dc.subject	Homogeneous catalysts
ISSN dc.identifier.issn	1563-5325
İlk Sayfa dc.identifier.startpage	993
Son Sayfa dc.identifier.endpage	999
Dergi Adı dc.relation.journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Dergi Sayısı dc.identifier.issue	7
Dergi Cilt dc.identifier.volume	191
Tek Biçim Adres (URI) dc.identifier.uri	https://hdl.handle.net/20.500.14114/8218
DOI Numarası dc.identifier.doi	https://doi.org/10.1080/10426507.2015.1119827
İndekslenen Platformlar dc.source.database	Web of Science

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